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bestofwikipedia:

The Leidenfrost effect is a phenomenon in which a liquid, in near contact with a mass significantly hotter than the liquid’s boiling point, produces an insulating vapor layer which keeps that liquid from boiling rapidly. This is most commonly seen when cooking; one sprinkles drops of water in a skillet to gauge its temperature—if the skillet’s temperature  is at or above the Leidenfrost point, the water skitters across the metal and takes longer to evaporate than it would in a skillet that is above boiling temperature, but below the temperature of the Leidenfrost point.